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https://elib.bsu.by/handle/123456789/342280| Title: | Adsorption of I2 by Macrocyclic Polyazadithiophenolato ComplexesMediated by Charge-Transfer Interactions |
| Authors: | Golecki, Matthias Beyer, Norman Steinfeld, Gunther Lozan, Vasile Voitekhovich, Sergei Sehabi, Muhamed Mçllmer, Jens Krüger, Hans-Jçrg Kersting, Berthold |
| Keywords: | ЭБ БГУ::ЕСТЕСТВЕННЫЕ И ТОЧНЫЕ НАУКИ ЭБ БГУ::ЕСТЕСТВЕННЫЕ И ТОЧНЫЕ НАУКИ::Химия |
| Issue Date: | 30-Jul-2014 |
| Citation: | Golecki M, Beyer N, Steinfeld G, Lozan V, Voitekhovich S, Sehabi M, et al. Adsorption of I2 by Macrocyclic Polyazadithiophenolato Complexes Mediated by Charge‐Transfer Interactions. Angewandte Chemie International Edition. 2014 Jul 30;53(37):9949–52. |
| Abstract: | The macrocyclic complex [Ni2 (L)(OAc)]ClO4 (1)adsorbs up to 17 molar equivalents (> 270 wt %) of iodine,although it does not exhibit permanent porosity. Vibrationalspectroscopic and crystallographic studies reveal that two I2molecules are captured by means of thiophenolate!I2 charge-transfer interactions, which enable the diffusion and sorption offurther I2 molecules in a polyiodide-like network. The efficientsorption and desorption characteristics make this materialsuitable for accommodation, sensing, and slow release of I2 |
| URI: | https://elib.bsu.by/handle/123456789/342280 |
| DOI: | 10.1002/anie.201405199 |
| Licence: | info:eu-repo/semantics/openAccess |
| Appears in Collections: | Статьи сотрудников НИИ ФХП |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| Angew Chem Int Ed - 2014 - Golecki - Adsorption of I2 by Macrocyclic Polyazadithiophenolato Complexes Mediated by.pdf | 719,91 kB | Adobe PDF | View/Open |
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