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Заглавие документа: | On the N-Arylation of Acetamide Using 2-, 3- and 1’-Substituted Iodoferrocenes |
Авторы: | Kadari, Lingaswamy Erb, William Halauko, Yury S Ivashkevich, Oleg A. Matulis, Vadim E. Lyakhov, Dmitry Roisnel, Thierry Krishna, Palakodety Radha Mongin, Florence |
Тема: | ЭБ БГУ::ЕСТЕСТВЕННЫЕ И ТОЧНЫЕ НАУКИ::Математика |
Дата публикации: | 2021 |
Издатель: | Wiley-VCH Verlag |
Библиографическое описание источника: | Eur J Inorg Chem 2021;2021(4):377-391. |
Аннотация: | Various 2-, 3- and 1’-substituted iodoferrocenes were reacted with acetamide in the presence of copper(I) iodide (1 equiv), N,N’-dimethylethylenediamine (1 equiv), tripotassium phosphate (2 equiv) in dioxane at 90 °C for 14 h, and allowed a large range of original 1,2-, 1,3- and 1,1’-disubstituted ferrocenes to be obtained. The results were compared as a function of the substituent and its position on the ring. DFT calculations revealed higher activation barrier for the oxidative addition in the ferrocene series when compared with classical planar aromatics. Structure-property relationships were applied to rationalize the reactivity of the different iodoferrocenes. |
URI документа: | https://elib.bsu.by/handle/123456789/289448 |
DOI документа: | 10.1002/ejic.202000904 |
Scopus идентификатор документа: | 85097885674 |
Финансовая поддержка: | This work was supported by the Université de Rennes 1 and CNRS. The authors would like to thank Rennes Métropole for a doctoral mobility fellowship (L. K.) and Région Bretagne for a postdoctoral fellowship grant (L. K.). We gratefully acknowledge the Fonds Européen de Développement Régional (FEDER; D8 Venture Bruker AXS diffractometer), Thermofisher (generous gift of 2,2,6,6‐tetramethylpiperidine), and the Hyderabad CSIR‐Indian Institute of Chemical Technology for recording the High Resolution Mass Spectra (HRMS). This research has been performed as part of the Indo‐French ‘Joint Laboratory for Natural Products and Synthesis towards Affordable Health’. |
Лицензия: | info:eu-repo/semantics/openAccess |
Располагается в коллекциях: | Статьи сотрудников НИИ ФХП |
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Файл | Описание | Размер | Формат | |
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on-the-n-arylation-of-acetamide-using-2-3-and-1-substituted-iodoferrocenes.pdf | 944,36 kB | Adobe PDF | Открыть |
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