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Please use this identifier to cite or link to this item: https://elib.bsu.by/handle/123456789/20743
Title: СИНТЕЗ И СТРОЕНИЕ НОВЫХ КОМПЛЕКСНЫХ СОЕДИНЕНИЙ ПАЛЛАДИЯ(II) С N-ЗАМЕЩЕННЫМИ ТЕТРАЗОЛАМИ
Authors: Серебрянская, Т. В.
Гапоник, П. Н.
Ляхов, А. С.
Ивашкевич, О. А.
Issue Date: 2008
Publisher: Минск: БГУ
Citation: Свиридовские чтения: сб. ст. Вып. 4.
Abstract: The interaction between palladium(II) chloride and several N-substituted mono- and dinuclear tetrazoles was investigated for the first time. 1-Methyl-, 1-phenyl-, 2-methyl- and 2-tert-butyl-substituted 5-aminotetrazoles as well as 1 (2 hydroxyethyl)tetrazole and 1,5-diaminotetrazole were shown to react with palladium dichloride in water or water-ethanol mixture (рН = 1–2) to give crystalline complexes PdL2Cl2 in high yield. In analogous conditions bis(2-methyltetrazol-5-yl)amine forms complex Pd(HL7)Cl2 while 1,3-bis(2-methyltetrazol-5-yl)triazene and 1,3-bis(2-tert-butyltetrazol-5-yl)triazene deprotonate to give complexes PdLCl. Products were characterized by elemental analysis and IR-spectroscopy. The structure of complex trans-Pd(L1)2Cl2 was established by X-ray analysis.
URI: http://elib.bsu.by/handle/123456789/20743
Appears in Collections:Статьи химического факультета

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