Please use this identifier to cite or link to this item:
https://elib.bsu.by/handle/123456789/241803
Title: | Photoluminescence kinetics for monitoring photoinduced processes in perovskite solar cells |
Authors: | Mahon, Natallia S. Korolik, Olga V. Khenkin, Mark V. Arnaoutakis, Georgios E. Galagan, Yulia Soriūtė, Vaiva Litvinas, Džiugas Ščajev, Patrik Katz, Eugene A. Mazanik, Alexander V. |
Keywords: | ЭБ БГУ::ЕСТЕСТВЕННЫЕ И ТОЧНЫЕ НАУКИ::Физика |
Issue Date: | 1-Jan-2020 |
Publisher: | Elsevier Ltd. |
Citation: | Solar Energy. – 2020. – Volume 195 – Pages 114–120. |
Abstract: | The research on halide perovskites is in its peak activity at the moment due to the material’s potential application in photovoltaics. It is well known that slow processes, from seconds to minutes, are very significant in perovskite films and devices as compared to conventional photovoltaic materials. The kinetics of photoluminescence (PL) is informative data for studying such processes. In particular, tracing the change in PL intensity under continuous laser excitation provides information on charge carriers’ recombination and the efficiency of their extraction from the absorber layer. Although widely available, this method was applied mainly for the research on thin films. However, monitoring PL kinetics on complete solar cells as well as on incomplete device stacks at each fabrication and lifespan stage can provide an important information on the device optimization and determination of the layers and interfaces that limit device efficiency and stability. Here, we demonstrate the advantages of the method by tracing the evolution of PL kinetics upon: (1) varying perovskite composition (MAPbI3, Cs0.15FA0.85PbI2.7Br0.3, Cs0.05(MA0.15FA0.85)0.95PbI2.55Br0.45); (2) layer-by-layer stack construction of Cs0.15FA0.85PbI2.7Br0.3-based solar cell and (3) the device on-shelf degradation. In this way, information on charge carrier recombination, diffusion and extraction is revealed purely by optical, contactless and non-destructive means. |
URI: | http://elib.bsu.by/handle/123456789/241803 |
DOI: | https://doi.org/10.1016/j.solener.2019.11.050 |
Appears in Collections: | Кафедра физики твердого тела и нанотехнологий (статьи) |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
manuscript_Mahon-for library.docx | 25,86 MB | Microsoft Word XML | View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.