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https://elib.bsu.by/handle/123456789/196780| Title: | Исследование строения комплексных соединений тетрафторбората меди (II) c n-замещенными тетразолами методом ИК-спектроскопии |
| Authors: | Гапоник, Павел Николаевич Дегтярик, Михаил Михайлович Науменко, Валентина Николаевна Ивашкевич, Олег Анатольевич |
| Keywords: | ЭБ БГУ::ЕСТЕСТВЕННЫЕ И ТОЧНЫЕ НАУКИ::Химия |
| Issue Date: | 2001 |
| Publisher: | Минск : БГУ |
| Citation: | Вестник Белорусского государственного университета. Сер. 2, Химия. Биология. География. – 2001. - № 1. – С. 10-12. |
| Abstract: | Coordination of the BF4 anion with central atom in complexes of copper (II) tetrafluoroborate with Tethyl-(1-ET), 2-ethyl- (2-ET), 1-butyl- (TBuT)1 1-phenyl- (TPhT)1 1-fert-butyl- (Tf-BuT) and 2-fert-butyttetrazdes (2-f-BuT) have been investigated using IR spectroscopy It was established that in complexes with ratio Cu/L = 1/4, (1^1-ET 2-ET, Tf-BuT and 2-f-BuT) two BF; anion are bonded with copper (II) atom via fluorin atom whereas in complexes with ratio Cu/L = 1/6, (L=1-ET, 1-BuT) two BF4 anions are not coordinated. Complex Cu(I-PhT)5(BF4)2 have intermediate structure and BF . anions are in both tree and coordinated forms. |
| URI: | http://elib.bsu.by/handle/123456789/196780 |
| ISSN: | 0372-5340 |
| Appears in Collections: | 2001, №1 (февраль) |
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