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https://elib.bsu.by/handle/123456789/292546
Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Pozdnyakov, A. O. | - |
dc.contributor.author | Pushkarchuk, A. L. | - |
dc.contributor.author | Kuten, S. A. | - |
dc.contributor.author | Babichev, L. F. | - |
dc.date.accessioned | 2023-01-23T07:22:38Z | - |
dc.date.available | 2023-01-23T07:22:38Z | - |
dc.date.issued | 2021 | - |
dc.identifier.citation | Nonlinear Phenomena in Complex Systems. - 2021. - Vol. 24, N 4. - P. 365-369 | ru |
dc.identifier.issn | 1561-4085 | - |
dc.identifier.uri | https://elib.bsu.by/handle/123456789/292546 | - |
dc.description.abstract | Mass-spectrometric thermal decomposition experiments with submicron films of neat polymethylmethacrylate (PMMA), and PMMA-fullerene composite (PMMA-C60) after UV irradiation are discussed. The experiment registers thermal desorption mass spectra (TDMS), that is the monomer desorption rate versus time upon gradual heating the PMMA films in a given heating regime. The spectra provide information on the amount of the monomer desorbed at different decomposition stages upon heating the given amount of film material as well as on the spectral shape changes. It is shown that both amount of monomer and the TDMS spectral shape are sensitive to the presence of fullerene and UV irradiation. The experimental results are discussed in terms of quantum chemical models of binding. The DFT/B3LYP-D3/def2/J RIJCOSX level of theory was used. The MMA-C60 structures which can yield different amounts of monomer have been compared. | ru |
dc.language.iso | en | ru |
dc.publisher | Minsk : Education and Upbringing | ru |
dc.rights | info:eu-repo/semantics/openAccess | ru |
dc.subject | ЭБ БГУ::ЕСТЕСТВЕННЫЕ И ТОЧНЫЕ НАУКИ::Физика | ru |
dc.title | PMMA – C60 composite: thermal decomposition experiments in mass spectrometer and quantum chemical modeling | ru |
dc.type | article | ru |
dc.rights.license | CC BY 4.0 | ru |
dc.identifier.DOI | 10.33581/1561-4085-2021-24-4-365-369 | - |
Appears in Collections: | 2021. Volume 24. Number 4 |
Files in This Item:
File | Description | Size | Format | |
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v24no4p365.pdf | 1,18 MB | Adobe PDF | View/Open |
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